Le groupe de Radiochimie entreprend des recherches fondamentales et appliquées dans des domaines à forte demande sociétale. Les thèmes développés concernent en particulier l’aval du cycle électronucléaire. Le groupe est spécialisé dans la chimie des actinides (An) et des lanthanides (Ln) ; de leur spéciation en solution pour la recherche de nouveaux procédés d’extraction et de leur comportement dans l’environnement pour les problèmes liés à leur stockage. Les activités développées sur l’interaction des rayonnements ionisants avec la matière, dans un contexte de santé, trouvent des applications directes en dosimétrie (radioprotection, radiothérapie) ou encore en imagerie médicale.

Responsable scientifique : Quentin RAFFY

Membres de l’équipe Radiochimie

Aurelia ARNONE

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Mirella DEL NERO

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Catherine GALINDO

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Sylvia GEORG

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Christophe HOFFMANN

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Jean-Marc JUNG

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Quentin RAFFY

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Henry RUTT

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Galyna ZYMA

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Publications récentes

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Mazan, V.; Boltoeva, M.
Aqueous N-H acid bis(trifluoromethylsulfonyl) imide Solution – C(4)mim Tf2N Ionic Liquid Biphasic System: an Original Investigation by Diffusion Ordered Spectroscopy Nuclear Magnetic Resonance
Journal of Fluorine Chemistry, 2021, 245, 109782. (10.1016/j.jfluchem.2021.109782).

Del Nero M.; Montavon, G.
Les radionucléides dans l’environnement : Enjeux sociétaux et défis scientifiques.
L’Actualité Chimique, 2021, 460-461, nov.-16. ().

Zante, G.; Boltoeva, M.; Masmoudi, A.; Barillon, R.; Trebouet, D.
Supported ionic liquid and polymer inclusion membranes for metal separation
Separation and Purification Reviews, 2021, 51(1), 100-116. (10.1080/15422119.2020.1846564).

Masmoudi, A.; Zante, G.; Trebouet, D.; Barillon, R.; Boltoeva, M.
Solvent extraction of lithium ions using benzoyltrifluoroacetone in new solvents
Separation and Purification Technology, 2021, 255, 117653. (10.1016/j.seppur.2020.117653).

Quaranta, G.; Bloundi, M. K.; Duplay, J.; Clauer, N.
The eutrophication process of Nador’s lagoon (Morocco) evaluated by the Life Cycle Impact Assessment method
Arabian Journal of Geosciences, 2021, 14(5), . (10.1007/s12517-021-06685-4).

Kusumoto T.; Kanasaki M.; Ishikawa I.; Barillon R.; Honda Y.
Examining features of radiation-induced damage to PADC observed using FT-IR analysis: Radiation tolerance of methine groups at three-way junctions
Radiation Measurements, 2021, 147, 106645. (10.1016/j.radmeas.2021.106645).

Baba, K.; Kusumoto, T.; Okada, S.; Ogawara, R.; Kodaira, S.; Raffy, Q.; Barillon, R.; Ludwig, N.; Galindo, C.; Peaupardin, P.; Ishikawa, M.
Quantitative estimation of track segment yields of water radiolysis species under heavy ions around Bragg peak energies using Geant4-DNA
Scientific Reports, 2021, 11(1), 1524. (10.1038/s41598-021-81215-6).

Tereshatov, E. E.; Mazan, V.; Boltoeva, M.; Folden, C. M.
Effect of hydrophobic ionic liquids aqueous solubility on metal extraction from hydrochloric acid media: Mathematical modelling and trivalent thallium behavior
Separation and Purification Technology, 2021, 255, 117650. (10.1016/j.seppur.2020.117650).

Triaux, Zélie; Petitjean, Hugues; Marchioni, Eric; Boltoeva, Maria; Marcic, Christophe
Deep eutectic solventÐbased headspace single-drop microextraction for the quantification of terpenes in spices
Analytical and Bioanalytical Chemistry, 2020, 412(4), 933-948. (10.1007/s00216-019-02317-9).

Zante, G.; Trébouet, D.; Boltoeva, M.
Solvent extraction of lithium from simulated shale gas produced water with a bifunctional ionic liquid
Applied Geochemistry, 2020, 123, 104783. (10.1016/j.apgeochem.2020.104783).

Saulnier, A.; Bleu, J.; Boos, A.; El Masoudi, I.; Ronot, P.; Zahn, S.; Del Nero, M.; Massemin, S.
Consequences of trace metal cocktail exposure in zebra finch (Taeniopygia guttata) and effect of calcium supplementation
Ecotoxicology and Environmental Safety, 2020, 193, 110357. (10.1016/j.ecoenv.2020.110357).

Turanov, A.N.; Karandashev, V. K.; Boltoeva, M.
Solvent extraction of intra-lanthanides using a mixture of TBP and TODGA in ionic liquid
Hydrometallurgy, 2020, 195, 105367. (10.1016/j.hydromet.2020.105367).

Saputra A. M.; Del Nero M.; Quaranta G.; Courson O.
Understanding of tritium behavior towards sediments in aquatic ecosystem
International Journal of Advances in Science, Engineering and Technology (IJASEAT), Universal Paper ID SF-CELS-JKRT-29109-226., 2020, , . (10.4108/eai.23-11-2019.2301619).

Zante, G.; Boltoeva, M.; Masmoudi, A.; Barillon, R.; Trébouet, D.
Highly selective transport of lithium across a supported liquid membrane
Journal of Fluorine Chemistry, 2020, 236, 109593. (10.1016/j.jfluchem.2020.109593).

Zante, G.; Masmoudi, A.; Barillon, R.; Trébouet, D.; Boltoeva, M.
Separation of lithium, cobalt and nickel from spent lithium-ion batteries using TBP and imidazolium-based ionic liquids
Journal of Industrial and Engineering Chemistry, 2020, 82, 269-277. (10.1016/j.jiec.2019.10.023).

Zante, G.; Braun, A.; Masmoudi, A.; Barillon, R.; Trébouet, D.; Boltoeva, M.
Solvent extraction fractionation of manganese, cobalt, nickel and lithium using ionic liquids and deep eutectic solvents
Minerals Engineering, 2020, 156, 106512. (10.1016/j.mineng.2020.106512).

Zante, G.; Boltoeva, M.; Masmoudi, A.; Barillon, R.; Trebouet, D.
Selective separation of cobalt and nickel using a stable supported ionic liquid membrane
Separation and Purification Technology, 2020, 252, 117477. (10.1016/j.seppur.2020.117477).

Masmoudi, A.; Zante, G.; Trébouet, D.; Barillon, R.; Boltoeva, M.
Understanding the Mechanism of Lithium Ion Extraction Using Tributyl Phosphate in Room Temperature Ionic Liquid
Solvent Extraction and Ion Exchange, 2020, 38(7), 777-799. (10.1080/07366299.2020.1788201).

Zante G.; Boltoeva M.
Review on Hydrometallurgical Recovery of Metals with Deep Eutectic Solvents
Sustainable Chemistry, 2020, 1 (3), 238-255. (10.3390/suschem1030016).

Edgecomb, J. M.; Tereshatov, E. E.; Zante, G.; Boltoeva, M.; Folden, C. M.
Hydrophobic amine-based binary mixtures of active pharmaceutical and food grade ingredients: characterization and application in indium extraction from aqueous hydrochloric acid media
Green Chemistry, 2020, 22(20), 7047-7058. (10.1039/d0gc02452j).

Volia, M. F.; Tereshatov, E. E.; Boltoeva, M.; Folden, C. M.
Indium and thallium extraction into betainium bis(trifluoromethylsulfonyl)imide ionic liquid from aqueous hydrochloric acid media
New Journal of Chemistry, 2020, 44(6), 2527-2537. (10.1039/c9nj04879k).

Kusumoto T.; Barillon R.; Okada S.; Yamauchi T.; Kodaira S.
Improved criterion of the mechanism for forming latent tracks in poly(allyl diglycol carbonate) based on the number of interactions induced by secondary electrons.
Radiation Measurements, 2020, 138, 106445. (10.1016/j.radmeas.2020.106445).

Kusumoto, T.; Okada, S.; Kurashige, H.; Kobayashi, K.; Fromm, M.; Raffy, Q.; Ludwig, N.; Kanasaki, M.; Oda, K.; Honda, Y.; Tojo, S.; Groetz, J. E.; Ogawara, R.; Kodaira, S.; Barillon, R.; Yamauchi, T.
Evidence for a critical dose above which damage to carbonate ester bonds in PADC appear after gamma ray and ultra soft X-ray exposures
Radiation Physics and Chemistry, 2020, 170, 108628. (10.1016/j.radphyschem.2019.108628).

Kusumoto, T.; Ogawara, R.; Ludwig, N.; Raffy, Q.; Kodaira, S.
Water radiolysis with thermal neutrons, fast neutrons and contamination gamma rays in the accelerator based thermal neutron field: Time dependence of hydroxyl radical yields
Radiation Physics and Chemistry, 2020, 174, 108978. (10.1016/j.radphyschem.2020.108978).

Zante, G.; Boltoeva, M.; Masmoudi, A.; Barillon, R.; Trebouet, D.
Lithium extraction from complex aqueous solutions using supported ionic liquid membranes
Journal of Membrane Science, 2019, 580, 62-76. (10.1016/j.memsci.2019.03.013).

Volia, M. F.; Tereshatov, E. E.; Mazan, V.; Folden, C. M.; Boltoeva, M.
Effect of aqueous hydrochloric acid and zwitterionic betaine on the mutual solubility between a protic betainium-based ionic liquid and water
Journal of Molecular Liquids, 2019, 276, 296-306. (10.1016/j.molliq.2018.11.136).

Kusumoto, T.; Barillon, R.; Yamauchi, T.
Application of Radial Electron Fluence around ion tracks for the description of track response data of polyethylene terephthalate as a polymeric nuclear track detector
Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, 2019, 461, 260-266. (10.1016/j.nimb.2019.10.007).

Kusumoto, T.; Ngono-Ravache, Y.; Balanzat, E.; Galindo, C.; Ludwig, N.; Raffy, Q.; Yamauchi, T.; Kodaira, S.; Barillon, R.
The role of molecular and radical mobility in the creation of CO2 molecules and OH groups in PADC irradiated with C and O ions
Polymer Degradation and Stability, 2019, 164, 102-108. (10.1016/j.polymdegradstab.2019.04.007).

Makhlouf, A.; Quaranta, G.; Kardache, R.
Energy consumption and greenhouse gas emission assessment in the Algerian sector of fertilisers production with life cycle assessment
International Journal of Global Warming, 2019, 18(1), 16-36. (10.1504/ijgw.2019.100173).

Tereshatov, E. E.; Boltoeva, M.; Mazan, V.; Baley, C.; Folden, C. M.
Hydrophobic polymerized ionic liquids for trace metal solid phase extraction: thallium transfer from hydrochloric acid media
New Journal of Chemistry, 2019, 43(23), 8958-8969. (10.1039/c9nj00689c).

Fromm M.; Kodaira S.; Kusumoto T.; Barillon R.; Yamauchi T.
Role of intermediate species in the formation of ion tracks in PADC: A review
Polymer Degradation and Stability, 2019, 161, 213 – 224. (10.1016/j.polymdegradstab.2019.01.028).

Walaszek, M.; Del Nero, M.; Bois, P.; Ribstein, L.; Courson, O.; Wanko, A.; Laurent, J.
Sorption behavior of copper, lead and zinc by a constructed wetland treating urban stormwater
Applied Geochemistry, 2018, 97, 167-180. (10.1016/j.apgeochem.2018.08.019).

Mazan, V.; Boltoeva, M.
Aqueous acidic solution – ionic liquid biphasic system: An original investigation by diffusion ordered spectroscopy nuclear magnetic resonance
Journal of Molecular Liquids, 2018, 269, 684-693. (10.1016/j.molliq.2018.08.086).

Ternova, D.; Ouadi, A.; Mazan, V.; Georg, S.; Boltoeva, M.; Kalchenko, V.; Miroshnichenko, S.; Billard, I.; Gaillard, C.
New Ionic Liquid Based on the CMPO Pattern for the Sequential Extraction of U(VI), Am(III) and Eu(III)
Journal of Solution Chemistry, 2018, 47(8), 1309-1325. (10.1007/s10953-018-0730-3).

Kusumoto, T.; Bitar, Z. E. L.; Okada, S.; Gillet, P.; Arbor, N.; Kanasaki, M.; Mori, Y.; Oda, K.; Nourreddine, A. M.; Kurashige, H.; Fromm, M.; Cloutier, P.; Bass, A. D.; Sanche, L.; Kodaira, S.; Barillon, R.; Yamauchi, T.
Radial electron fluence around ion tracks as a new physical parameter for the detection threshold of PADC using Geant4-DNA toolkit
Radiation Measurements, 2018, 118, 50-53. (10.1016/j.radmeas.2018.08.015).

Boltoeva, M.; Gaillard, C.; Georg, S.; Karandashev, V. K.; Turanov, A. N.
Speciation of uranium(VI) extracted from acidic nitrate media by TODGA into molecular and ionic solvents
Separation and Purification Technology, 2018, 203, 43770. (10.1016/j.seppur.2018.04.003).

Mukhtar, H.; Montgomery, P.; Anstotz, F.; Barillon, R.; Rubin, A.
Immersion white light scanning interferometry using elastic polymer path length compensation
Optical Micro- and Nanometrology Vii, Gorecki, C., Asundi, A.K. & Osten, W., ed(s). Bellingham, 2018, , . (10.1117/12.2315474).

Fleury, G.; Del Nero, M.; Barillon, R.
Effect of mineral surface properties (alumina, kaolinite) on the sorptive fractionation mechanisms of soil fulvic acids: Molecular-scale ESI-MS studies
Geochimica et Cosmochimica Acta, 2017, 196, 42736. (10.1016/j.gca.2016.09.029).

Kusumoto, T.; Terashita, Y.; Mori, Y.; Kanasaki, M.; Oda, K.; Yamauchi, T.; Kodaira, S.; Kitamura, H.; Honda, Y.; Tojo, S.; El Bitar, Z.; Arbor, N.; Raffy, Q.; Barillon, R.; Groetz, J.E.; Fromm, M.
Studies on latent tracks in PADC nuclear track detector
Hoshasen-Ionizing radiation, 2017, 42(3), 73-82. ().

Mazan, V.; Boltoeva, M.
Insight into the ionic interactions in neat ionic liquids by Diffusion Ordered Spectroscopy Nuclear Magnetic Resonance
Journal of Molecular Liquids, 2017, 240, 74-79. (10.1016/j.molliq.2017.05.021).

Fleury, G.; Del Nero, M.; Barillon, R.
Molecular fractionation of a soil fulvic acid (FA) and competitive sorption of trace metals (Cu, Zn, Cd, Pb) in hematite-solution systems: effect of the FA-to-mineral ratio
RSC Advances, 2017, 7(68), 43090-43103. (10.1039/c7ra06838g).

Gaillard C.;, Boltoeva M.; Ouadi A.; MazanV.; Georg S.
Ionic liquids for the liquid liquid extraction of uranium(VI)
Actinides, 2017, , . ().

Souici, M.; Khalil, T. T.; Muller, D.; Raffy, Q.; Barillon, R.; Belafrites, A.; Champion, C.; Fromm, M.
Single- and Double-Strand Breaks of Dry DNA Exposed to Protons at Bragg-Peak Energies
Journal of Physical Chemistry B, 2017, 121(3), 497-507. (10.1021/acs.jpcb.6b11060).

Tereshatov, E. E.; Boltoeva, M. Y.; Folden, C. M.
First evidence of metal transfer into hydrophobic deep eutectic and low-transition-temperature mixtures: indium extraction from hydrochloric and oxalic acids
Green Chemistry, 2016, 18(17), 4616-4622. (10.1039/c5gc03080c).

Melchior, A.; Gaillard, C.; Lanas, S. G.; Tolazzi, M.; Billard, I.; Georg, S.; Sarrasin, L.; Boltoeva, M.
Nickel(II) Complexation with Nitrate in Dry [C4mim][ Tf2N] Ionic Liquid: A Spectroscopic, Microcalorimetric, and Molecular Dynamics Study
Inorganic Chemistry, 2016, 55(7), 3498-3507. (10.1021/acs.inorgchem.5b02937).

Adam, V.; Loyaux-Lawniczak, S.; Labille, J.; Galindo, C.; Del Nero, M.; Quaranta G.
Aggregation behaviour of TiO2 nanoparticles in natural river water
Journal of Nanoparticle Research, 2016, 18, 13. (10.1007/s11051-015-3319-4).

Ternova, D.; Boltoeva, M.; Cointeaux, L.; Gaillard, C.; Kalchenko, V.; Mazan, V.; Miroshnichenko, S.; Mohapatra, P. K.; Ouadi, A.; Papaiconomou, N.; Petrova, M.; Billard, I.
Dramatic Changes in the Solubilities of Ions Induced by Ligand Addition in Biphasic System D2O/DNO3//[C1C4im][Tf2N]: A Phenomenological Study
Journal of Physical Chemistry B, 2016, 120(30), 7502-7510. (10.1021/acs.jpcb.6b05424).

Mazan, V.; Boltoeva, M. Y.; Tereshatov, E. E.; Folden, C. M.
Mutual solubility of water and hydrophobic ionic liquids in the presence of hydrochloric acid
RSC Advances, 2016, 6(61), 56260-56270. (10.1039/c6ra06791c).

Turanov, A. N.; Karandashev, V. K.; Boltoeva, M.; Gaillard, C.; Mazan, V.
Synergistic extraction of uranium(VI) with TODGA and hydrophobic ionic liquid mixtures into molecular diluent
Separation and Purification Technology, 2016, 164, 97-106. (10.1016/j.seppur.2016.03.004).

Chiodetta C.G. Cotelle S., Masfaraud JF, Toumi H., Quaranta G., Adani F., Radetski C.M.
Use of agro-industrial sludge amendment to remediate degraded soil : chemical and eco(geno)toxicological differences between fresh and stabilized sludge and establishment of application rates, Environ. Sci. Pollut. Res., 23 3018-3026
Environmental Science and Pollution Research, 2016, 23, 3018-3029. (10.1007/s11356-015-5310-0).

Tereshatov, E. E.; Boltoeva, M.; Mazan, V.; Volia, M. F.; Folden, C. M.
Thallium Transfer from Hydrochloric Acid Media into Pure Ionic Liquids
Journal of Physical Chemistry B, 2016, 120(9), 2311-2322. (10.1021/acs.jpcb.5b08924).

Gaillard, C.; Boltoeva, M.; Billard, I.; Georg, S.; Mazan, V.; Ouadi, A.
Ionic liquid-based uranium(VI) extraction with malonamide extractant: cation exchange vs. neutral extraction
RSC Advances, 2016, 6(74), 70141-70151. (10.1039/c6ra11345a).